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静岡県立大学教員データベース


教員情報詳細


氏名
永井 大介(NAGAI Daisuke)
出生年月
1974年10月
所属・職名
食品栄養科学部環境生命科学科(グリーンケミストリー研究室) 准教授
食品栄養環境科学研究院 准教授(兼務)
電話番号
054-264-5729
部屋番号
食品栄養科学部2号棟12502室
Eメールアドレス
daisukenagai@u-shizuoka-ken.ac.jp
研究シーズ集
https://www.u-shizuoka-ken.ac.jp/media/seeds2019-2020_086.pdf

学歴

1997年 明治大学理工学部工業化学科卒業
2002年 東京工業大学総合理工学研究科物質電子化学専攻博士後期課程修了

学位

工学博士(東京工業大学・2002年)

専門分野

高分子合成・高分子化学・環境化学

担当科目

反応有機化学、地域地球環境学特論(分担)、食品栄養環境科学概論(分担)、環境学総論(分担)、環境生命科学実験(分担)

主要研究テーマ

  • 新規重合反応の開発
  • 高効率レアメタル捕集ポリマーの合成
  • コンニャクグルコマンナンを用いたナノ材料の合成(共同研究)

所属学会

高分子学会
日本化学会

主な経歴

2005年9月 群馬大学理工学部化学・生物化学科 助教
2019年4月 静岡県立大学食品栄養科学部環境生命科学科 准教授

受賞歴

2018年 平成30年度リサイクル技術開発本多賞
2015年 第19回横山科学技術賞
2011年 (社)新化学発展協会 研究奨励賞(現新化学技術研究奨励賞)

主な社会活動

高分子学会 代議員 2014~現在
繊維学会 実行委員 2018~現在

主要研究業績

○学術論文
  1. D. Nagai,* K. Kobayashi, K. Nakamura, T. Yamanobe “One-Pot Exchange Reaction of Acyl Hydrazone Combined with Radical Polymerization of Styrene Derivatives Bearing Acyl Hydrazone Moieties” Journal of Polymer Science Part A: Polymer Chemistry 57, 2505-2510 (2019).
  2. T. Yamanobe,* H. Takeda, Y. Takada, D. Nagai, M. Yoneyama, H. Uehara, K. Takahashi “Structure and Physical Properties of Poly(lactic acid) and Cyclodextrin Composite” Journal of Inclusion Phenomena and Macrocyclic Chemistry 93, 117-126 (2019).
  3. D. Nagai,* H. Goto “Effective Heterogeneous Catalyst for Suzuki-Miyaura Cross-Coupling in Aqueous Media: Melamine Cyanurate Containing Pd Species” Bulletin of the Chemical Society of Japan 91, 147-152 (2018).
  4. Y. Maki, K. Sugawara, D. Nagai “Temperature Dependence of Electrophoretic Mobility and Hydrodynamic Radius of Microgels of Poly(N-isopropylacrylamide)” Gels 4, 37 (2018).
  5. 岩淵龍之介, 永井大介, 米山賢, 上原宏樹, 山延健, 眞中将一 “組成及び練り時間が熱可塑性エラストマーの物性と構造に与える影響” 高分子論文集 75, 337-346 (2018).
  6. R. Kato, G. Yamaguchi, D. Nagai, Y. Maki, K. Yoshiba, T. Yamamoto, T. Dobashi* “Adsorption Dynamics of Tannin on Deacetylated Electrospun Konjac Glucomannan Fabric” Soft Matter 14, 2712-2723 (2018).
  7. D. Nagai,* S. Imai “Development of a Homogeneous/Heterogeneous Metal Recovery System Based on Reversible Association/Dissociation between Tris(2-aminoethyl) amine and 1,4-Bis(hexafluoro--hydroxyisopropyl)benzene” Separation and Purification Technology 177, 1-7 (2017).
  8. D. Nagai,* T. Kimoto “A Highly Efficient Supramolecular Adsorbent for Precious Metal: Adsorption Behavior of PdII by Melamine Cyanurate” RSC Advances 6, 103304-103310 (2016).
  9. D. Nagai,* A. Nagashima, M. Mori “A Facile and High-Recovery System for Palladium(II) Ion Based on Complexation between Trithiocyanuric Acid and Melamine” Chemistry Letters 45, 1165-1167 (2016).
  10. D. Nagai,* T. Daimon “Recovery of Cs(I) by a Thermoresponsive Metal Recovery Polymer Consisting of an N-Isopropylacrylamide Unit and a Sodium Methacrylate” Polymer Bulletin 73, 1553-1564 (2016).
  11. D. Nagai,* A. Nakazato, H. Morinaga “Facile and Efficient Recovery of Mercury Based on Poly(amine-ester) Bearing Metal-Complexation and Acidic Solution-Soluble Groups” Polymer Journal 47, 761-765 (2015).
  12. D. Nagai,* T. Kuribayashi, H. Tanaka, H. Morinaga, H. Uehara, T. Yamanobe “A Facile, Selective, High Recovery System for Rare Metal Based onComplexation between Melamine and Cyanuric Acid” RSC Advances 5, 30133-30139 (2015).
  13. D. Nagai,* T. Daimon, S. Kawakami, K. Inoue “High-Recovery Material for Mercury Ions Based on a Polyallylamine Hydrogel with Thiourea Groups at Cross-linking Points” Industrial & Engineering Research Chemistry 53, 3300-3304 (2014).
  14. H. Morinaga,* Y. Kiyokawa, R. Fujikawa, D. Nagai, H. Morikawa “Partially Biobased Polyamphiphile bearing Reactive Epoxy Groups in the Side Chains and Its Application to the Hydrogel” Polymer Bulletin 71, 2421-2435 (2014).
  15. M. Mori,* T. Suzuki, T. Sugita, D. Nagai, K. Hirayama, M. Onozato,H. Itabashi “Heavy Metal Adsorptivity of Calcium-alginate-modified Diethylenetria-mine-silica Gel and Its Application to a Flow Analytical System Using Flame Atomic Absorption Spectrometry” Analytica Chimimca Acta 38, 272-282 (2014).
  16. D. Nagai,* M. Yoshida, T. Kishi, H. Morinaga, Y. Hara, S. Kawakami, K. Inoue “A Facile and High-Recovery Material for Rare-Metals Based on a Water-Soluble Polyallylamine with Side-Chain Thiourea Groups” Chemical Communications 49, 6852-6854 (2013).
  17. H. Morinaga,* Y. Kiyokawa, M. Kataoka, J. Masuda, D. Nagai, “Synthesis of Partially Biobased Polymer Bearing Reactive Epoxy Groups in the Side Chains by Radical Copolymerization of Limonene Oxide with Methyl Acrylate” Polymer Bulletin 70, 1113-1123 (2013).
  18. D. Nagai,* A. Suzuki, Y. Maki, H. Takeno “Reversible Chain Association/Dissociation via a CO2 Responsive Crosslinking/Decrosslinking System” Chemical Communications 47, 8856-8858 (2011).
  19. H. Morinaga,* Y. Ujihara, N. Yuto, D. Nagai, T. Endo “Controlled Polymerization of Epoxides: Metal-Free Ring-Opening Polymerization of Glycidyl Phenyl Ether Initiated by Tetra-n-butylammon-ium Fluoride in the Presence of Protic Compounds” Journal of Polymer Science Part A: Polymer Chemistry 49, 5210-5216 (2011).
  20. D. Nagai,* A. Suzuki, T. Kuribayashi “Synthesis of Hydrogels from Polyallylamine with Carbon Dioxide as Gellant: Development of Reversible CO2 Absorbent” Macromolecular Rapid Communications 32, 404-410 (2011).
  21. H. Morinaga,* Y. Ujihara, T. Yamanaka, D. Nagai, T. Endo “Metal-Free Ring-opening Polymerization of Glycidyl Phenyl Ether Initiated by Tetra-n-butylammonium Acetate and Its Application to the Hydroxyl Terminated Telechelic Polymer” Journal of Polymer Science Part A: Polymer Chemistry 49, 4092-4097 (2011).
  22. D. Nagai,* T. Imazeki, H. Morinaga, H. Nakabayashi “Synthesis of a Rare-metal Adsorbing Polymer by Three-component Polyaddition of Diamines, Carbon Disulfide, and Diacrylates in an Aqueous/Organic Biphasic Medium” Journal of Polymer Science Part A: Polymer Chemistry 48, 5968-5973 (2010).
  23. H. Morinaga,* A. Matsumoto, T. Matsuda, D. Nagai, T. Endo “Ring-Opening Polymerization of Glycidyl Phenyl Ether Initiated by Tetra-n-butylammonium Halides as Metal-Free Initiators and Application of Its Polymer System to Networked Polymers”Journal of Network Polymer, Japan 31, 272-277 (2010).
  24. D. Nagai,* T. Imazeki, H. Morinaga, H. Oku, K.-I. Kasuya “Three-component Polyaddition of Diamines, Carbon Disulfide, and D-iacrylates in Water” Journal of Polymer Science Part A: Polymer Chemistry 48, 845-851(2010).
  25. D. Nagai, H. Kawakami, R. Imai, T. Endo* “Synthesis and Properties of Hydrogels Obtained by Crosslinking Pol-y(allylamine) with Carbon Disulfide in Water” Journal of Network Polymer, Japan 30, 200-206 (2009).
  26. K.-I. Kasuya,* N. Ishii, Y. Inoue, K. Yazawa, T. Tagaya, T. Yotsumoto, J-I. Kazahaya, D. Nagai “Characterization of a Mesophilic Aliphatic-aromatic Copolyester–degr-ading Fungus” Polymer Degradation and Stability 47, 1190-1196 (2009).
  27. D. Nagai, A. Fujii, M. Tanaka, B. Ochiai, A. Sudo, T. Endo* “Anionic Polymerization of Methacrylates by Samarium (III) Enolate on Networked Polystyrene: Effect of Its Sterically Confined Environment on Poltmerization Behavior” Journal of Polymer Science Part A: Polymer Chemistry 47, 1510-1521 (2009).
  28. D. Nagai, T. Endo* “Synthesis of 1H-quinazoline-2,4-diones from 2-Aminobenzonitriles by Fixation of Carbon Dioxide with Amidine Moiety Supported Polymer at Atmospheric Pressure” Journal of Polymer Science Part A: Polymer Chemistry 47, 653-657 (2009).
  29. D. Nagai, K. Yokota, T. Ogawa, B. Ochiai, T. Endo* “Cationic Ring-Opening Copolymerization Behavior of Trioxane and Seven-Membered Cyclic Carbonate” Journal of Polymer Science Part A: Polymer Chemistry 46, 733-739 (2008).
  30. B. Ochiai, K. Yokota, A. Fujii, D. Nagai, T. Endo* “Reversible Trap-Release of CO2 by Polymers Bearing DBU and DBN Moieties” Macromolecules 41, 1229-1236 (2008).
  31. D. Nagai, A. Fujii, B. Ochiai, A. Sudo, T. Endo* “Solid-Supported Synthesis of Amphiphilic Block Copolymer from Methacrylates” Journal of Polymer Science Part A: Polymer Chemistry 46, 1990-1997 (2008).
  32. 永井 大介,* 土橋 司, 長澤 尚胤, 三友 宏志 “バイオマックス®の放射線照射挙動とその生分解性” 繊維学会誌 64, 132-135 (2008).
  33. N. Ishii, Y. Inoue, T. Tagaya, H. Mitomo, D. Nagai, K.-I. Kasuya* “Isolation and Characterization of Poly(butylenes succinate)-degrading Fungi” Polymer Degradation and Stability 95, 883-888 (2008).
  34. T. M. Quynh, H. Mitomo,* D. Nagai, L. Zhao “Radiation-induced Crosslinking and Biodegradability of Poly(lactide)Stereocomplex” Transactions of the Materials Research Society of Japan 33, 443-446(2008).
  35. B. Ochiai, T. Nagasawa, Y. Asano, D. Nagai, A. Sudo, T. Endo* “Novel Analytical Method for the Cross-Linking Process: Infrared Thermographic Analysis of Thermally Latent Cationic Polymerization of a Spiroorthoester and a Bifunctional Oxetane for the Construction of a Low-Shrinkage Curing System” Journal of Polymer Science Part A: Polymer Chemistry, 45, 2820-2826 (2007).
  36. D. Nagai, A. Sudo, T. Endo* “Anionic Alternating Copolymerization of Ketene and Aldehyde: Control of Enantioselectivity by Bisoxazoline-type Ligand toward Synthesis of Optically Active Polyesters” Macromolecules 39, 8898-8900 (2006).
  37. D. Nagai, M. Nishida, B. Ochiai, T. Endo* “Synthesis and Properties of Poly(carbonate-co-ester)s Obtained by Cationic Ring-Opening Copolymerization Behavior of Spiroorthocarbonate and -Caprolactone” Journal of Polymer Science Part A: Polymer Chemistry 44, 2937–2942 (2006).
  38. D. Nagai, M. Nishida, B. Ochiai, K. Miyazaki, T. Endo* “Sequence Controlled Cationic Ring-Opening Copolymerization of Spi-roorthocarbonate and Oxetane” Journal of Polymer Science Part A: Polymer Chemistry 44, 3233–3241 (2006).
  39. 永井 大介, 八尾 隆慶, 西澤 理, 落合 文吾, 遠藤 剛* “メタクリル酸の低密度ポリエチレンへのグラフト重合と得られるグラフト共重合体の接着性” 日本接着学会誌 42, 231–237 ¬(2006).
  40. D. Nagai, M. Sato, B. Ochiai, T. Endo* “MALDI-TOF Mass Spectroscopic Analysis on Telechelic Polythiour-ethanes Obtained by Cationic Ring-Opening Polymerization of Six-Membered Cyclic Thiourethane” Journal of Polymer Science Part A: Polymer Chemistry 44, 4281-4289 (2006).
  41. D. Nagai, M. Nishida, T. Nagasawa, B. Ochiai, K. Miyazaki, T. Endo* “Non-Shrinking Networked Materials from Crosslinking Copolymeri-zation of Spiroorthocarbonate with Bifunctional Oxetane” Macromolecular Rapid Communication 27, 921-925 (2006).
  42. 落合 文吾, 八尾隆慶, 永井 大介, 遠藤 剛* “架橋性基と長鎖アルキル基を持つポリメタクリラートの合成とネットワーク型高疎水性フィルムへの応用” ネットワークポリマー 27, 70-76 (2006).
  43. B. Ochiai, K. Kuwabara, D. Nagai, T. Miyagawa, T. Endo* “Synthesis and Properties of Novel Polysulfone Bearing Exomethyle-ne Structure” European Polymer Journal 42, 1934-1938 (2006).
  44. D. Nagai, M. Sato, B. Ochiai, T. Endo* “Synthesis and Properties of the Polythiourethanes Obtained by Cationic Ring-Opening Polymerization of Cyclic Thiourethanes” Journal of Polymer Science Part A: Polymer Chemistry 44, 4795-4803 (2006).
  45. B. Ochiai, M. Matsuki, D. Nagai, T. Miyagawa, T. Endo* “Radical Polymerization Behavior of a Vinyl Monomer Bearing Five-membered Cyclic Carbonate Structure and Reactions of the Obtained Polymers with Amines” Journal of Polymer Science Part A: Polymer Chemistry 43, 584–592 (2005).
  46. B. Ochiai, K. Yoshii, D. Nagai, T. Endo* “Cationic Polymerization of a Seven-membered Cyclic Monothiocar-bonate, 1,3-Dioxepan-2-thione” Journal of Polymer Science Part A: Polymer Chemistry 43, 1014–1018 (2005).
  47. B. Ochiai, M. Matsuki, T. Miyagawa, D. Nagai, T. Endo* “Kinetic Study and Computational Studies on Aminolysis of Bicyclic Carbonates Bearing Alicyclic Structure Giving Alicyclic Hydroxyur-ethanes” Tetrahedron 61, 1835–1838 (2005).
  48. T. Endo,* K. Kakimoto, B. Ochiai, D. Nagai “Synthesis and Chemical-Recycling of a Polycarbonate Obtained by Anionic Ring-Opening Polymerization of a Bifunctional Cyclic Carbonate” Macromolecules 38, 8177–8182 (2005).
  49. A. Suzuki, D. Nagai, B. Ochiai, T. Endo* “Synthesis of Well-Defined Three-Armed Polystyrene Having Thiourethane–Isocyanurate as the Core Structure Drived from Trifunctional Five-Membered Cyclic Dithicarbonate” Journal of Polymer Science Part A: Polymer Chemistry 43, 5498–5505 (2005).
  50. 落合 文吾, 竹沢 昭郎, 小座間 梓, 伊東 聡子, 永井 大介, 宮川 豊治, 遠藤 剛* “側鎖に五員環カーボナート構造を有するポリマーのリジンによる架橋反応”ネットワークポリマー 26, 179–185 (2005).
  51. D. Nagai, A. Sudo, T. Endo* “Stereocontrolled Anionic Alternating Copolymerization of Ethylphe-nylketene with Benzaldehyde by a Bisoxazoline Ligand” Journal of Polymer Science Part A: Polymer Chemistry 42, 5384–5388 (2004).
  52. T. Endo,* D. Nagai, T. Monma, H. Yamaguchi, B. Ochiai “A Novel Construction of a Reversible Fixation-release System of C-arbon Dioxide by Amidines and Their Polymers” Macromolecules 37, 2007–2009 (2004).
  53. B. Ochiai, T. Iwamoto, T. Miyagawa, D. Nagai, T. Endo* “Solid-phase Incorporation of Gaseous Carbon Dioxide into Oxirane-containing Copolymers” Journal of Polymer Science Part A: Polymer Chemistry 42, 3812–3817 (2004).
  54. B. Ochiai, T. Iwamoto, T. Miyagawa, D. Nagai, T. Endo* “Direct Incorporation of Gaseous Carbon Dioxide into Solid-state Cop-olymer Containing Oxirane and Quarternary Ammonium Halide Structure as Self-catalytic Function” Journal of Polymer Science Part A: Polymer Chemistry 42, 4941–4947 (2004).
  55. B. Ochiai, K. Yoshii, D. Nagai, T. Endo* “Novel Anionic Ring-opening Polymerization of Seven-membered Monothiocarbonate Depending on Initiators” Macromolecules 37, 2329–2331 (2004).
  56. D. Nagai, M. Sato, B. Ochiai, T. Endo* “Controlled Cationic Ring-opening Polymerization of a Six-membered Cyclic Thiourethane” Macromolecules 37, 3523–3525 (2004).
  57. A. Suzuki, D. Nagai, B. Ochiai, T. Endo* “Facile Synthesis and Crosslinking Reaction of Trifunctional Five-m-embered Cyclic Carbonate and Dithiocarbonate” Journal of Polymer Science Part A: Polymer Chemistry 42, 5983–5989 (2004).
  58. A. Suzuki, D. Nagai, B. Ochiai, T. Endo* “Star-shaped Polymer Synthesis by Anionic Polymerization of Propylene Sulfide Based on Trifunctional Initiator Derived From Trifunctional Five-membered Cyclic Dithiocarbonate” Macromolecules 37, 8823–8824 (2004).
  59. D. Nagai, A. Sudo, T. Endo* “Alternating Copolymerization of Ethylphenylketene with Benzalde-hyde: Solvent- and Additive-controlled Stereospecific Formation of Polyester” Macromolecules 36, 3061–3065 (2003).
  60. D. Nagai, H. Kuramoto, A. Sudo, F. Sanda, T. Endo* “Novel Approach to Well-defined Synthesis of Polyester Bearing Phen-ol Moiety: Anionic Alternating Copolymerization of Ethylpheny-lketene with 4-(tert-Butyldimethylsilyloxy)benzaldehyde” Macromolecules 35, 6149-6153 (2002).
  61. D. Nagai, A. Sudo, F. Sanda, T. Endo* “Well-defined Synthesis of Crosslinkable Polyester by Living Anionic Alternating Copolymerization of Ethylphenylketene with 4-Allyl-oxybenzaldehyde” Journal of Network Polymer, Japan 22, 25–30 (2001).
  62. D. Nagai, A. Sudo, F. Sanda, T. Endo* “Novel Approach to Well-defined Polyester by Living Anionic Alternating Copolymerization of Ethylphenylketene with 4-Methoxyben-zaldehyde” Journal of Polymer Science Part A: Polymer Chemistry 39, 2078–2084 (2001).
  63. C.-L. Chen,* A. Potthast, T. Rosenau, J. S. Gratzl, A. G. Kirkman, D. Nagai, T. Miyakoshi “Laccase-catalyzed Oxidation of 1-(3,4-Dimethoxyphenyl)-1-propene using ABTS as Mediator” Journal of Molecular Catalysis B: Enzymatic 8, 213–219 (2000).
  64. 永井 大介, 長田 実, 垣花眞人* “錯体ゲル法によるデラフォサイト型酸化物CuMO2 (M = Fe, Al, Y,Ga)の合成” 粉体粉末冶金, 46, 185–188 (1999).

○総説
  1. 永井 大介, 落合 文吾, 遠藤 剛 “二酸化炭素の固定化反応と反応性高分子への応用” 高分子論文集 62, 158–166 (2005).
  2. T. Endo, D. Nagai “A Novel Construction of Ring-opening Polymerization and Chemical Recycling System” Macromolecular Symposia 226, 79–86 (2005).
  3. 永井 大介, 落合 文吾, 遠藤 剛 “CS2を原料とする新しい高分子材料の創製”未来材料 4, 24–29 (2004).
  4. 落合 文吾, 永井 大介, 遠藤 剛 “CO2を原料とする新しい高分子材料の創製”未来材料, 4, 22–27 (2004).

○受賞論文
  1. 永井大介 “平成30年度リサイクル技術開発本多賞 金属配位水溶性を基盤とした簡便かつ高回収レアメタル捕集材料の開発” 環境管理 54, 20-23 (2018).

○著書
  1. 永井大介, 他28名, レアメタル・希少金属リサイクル技術の最先端―ナノ・有機・メタラジーが広げるリサイクル技術―(担当:第3章第1節 ポリマーによるレアメタル回収), フロンティア出版, 原田幸明監修, p.77-83, 2011年.
  2. 永井大介, 他20名, 反応性高分子の新展開(担当:第2章 エポキシドと二硫化炭素を出発原料とする反応性ポリマーの設計 p.16-27, 第3章 炭酸ガスの固定化材料と応用, 第5章 易分解性ポリエステルの合成 p.74-85), シーエムシー出版, 遠藤剛監修, 2005年.

教育・研究に対する考え方

学生目線での教育・研究を心掛けている。

研究シーズ集に関するキーワード

高分子合成, 金属捕集材料, 有機-無機ハイブリット材料

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